The Media Of A Third Estate - 3243 Words

Current news media can no longer be considered to occupy the position of a fourth estate [Writer Name] [Institute Name] Current news media can no longer be considered to occupy the position of a fourth estate Introduction The new media distinctively associated with the nineteenth and twentieth century— the press, radio and television, the cinema and the record industry have traditionally been grouped together under the heading mass media’ and their study developed as a part of the sociology of mass communications (Jim, and William, 2007). At one level, this inherited vocabulary fulfils a useful descriptive function; people know what is being referred to when such terms as the media of mass communication are used. At another level, however, such terms may prove positively misleading. It is dear, for example, that the news media which are customarily referred to in this way resemble one another only superficially. The relationships between the state and broadcasting inst itutions, for example, are quite different from those which obtain between the state and the press or, different yet again, between the state and the cinema. Similarly, the relationship between industry and audience is quite differently articulated in the case of the record industry as compared with the film industry (Myria, 2014). Discussion Access to knowledge is important to the health of democracy for minimum two causes. First, it assures that people make responsible, informed options despite than actingShow MoreRelatedAnalysis of a Leading Real Estate Company in Virginia, CBPRO1423 Words   |  6 Pages CBPRO is a leading real estate company in Virginia, an independent franchisor of the Coldwell banker brand since 2001. CBPRO’s business focuses on residential real estate services such as selling, buying, and leasing houses; has 299 agents in 13 offices. The residential real estate industry is influenced by the ups and downs of the economy. In good times it fuels co nsumers confidence and spending, and in bad times consumers are cautious and not willing to invest in a house etc. CBPRO had aRead MoreCompany Profile Of ï  ± People960 Words   |  4 PagesMittal in 2004 to explore opportunities in New Media, Information Technology, Communication and Entertainment industries. The Group operates chiefly in the consumer Internet and mobile value-added services (VAS) sectors, and is made up of three companies—People Interactive, People Info.com and People Pictures. ï  ± People Interactive is the Consumer Internet arm of the Group and owns the extremely successful matrimonial portal Shaadi.com, along with real estate site Makaan.com and friendship and socialRead MoreOffice Market Study : Local Business Climate : Characteristics Of The Economic Base1655 Words   |  7 Pages the midtown Manhattan became increasingly popular to a variety of companies after the revitalization of the Broadway and the 911. While Lower Manhattan is the main financial center, Midtown is the country s largest commercial, entertainment and media center. Midtown Manhattan is now a growing center of finance, second in importance within the United States only to Lower Manhattan s Financial District. The proposed outline and logic of this report are as follows: firstly, the key influencing factorsRead MoreFacebooks Main Form Of Social Media Strategy For First Step Realty1240 Words   |  5 PagesSMM Strategy For First Step Realty our social media strategy was to mainly focus on utilizing our website and making it as informative as possible. Although we were not able to capture people on main social media platforms such as Twitter, Instagram or Snapchat we have a big presence on Facebook. Facebook is, and should continue to be, First Step’s main form of social media because it targets an older crowd that would be more prevalent to purchasing a home. Platforms such as Snapchat, Twitter,Read MoreSales Process For Real Estate Transactions1522 Words   |  7 PagesSales Process for Real Estate Transaction The real estate agents have the duty and the responsibility to represent clients throughout the sales process. Agents plays significant roles such as managing lists of contacts, advising clients on mortgages, pricing and market conditions, guiding buyers and sellers through the transaction process, generating lists of appropriate properties for buyers, mediating negotiations between sellers and buyers among others. In this paper, we focus on the sales processRead MoreResearch Methods1611 Words   |  7 Pagesasked in a person or through telephone call. This type also has few flaws- not all participants will answer to all questions, meaning they can skips some parts, it usually has a low return rate of answers and it also cannot present all society. 3 Third type of how to collect data for research is to conduct a questionnaire. Questionnaire similarly to survey is a method where information is gathered from a big amount of people and it is analysed quantitatively and systematically. The pluses of suchRead MoreBuilding A Real Estate Investor1246 Words   |  5 Pages Real estate Investor When I get out of high school I aspire to become a real estate investor because it pays well I like being able to turn something old into something new. Introduction Glass doors, hardwood floors, mosaic backsplashes, marble countertops and so much more. Flipping something old and upgrading it can be so rewarding financially. If you ve ever thought about remodeling old homes then real estate investing is the job for you. The following topics that I will address in theRead MoreStudying Finance At The University Of Florida1431 Words   |  6 Pagesfairly broad and versatile. Also, although I am not currently taking classes towards a minor, I plan on minoring in Real Estate. My brother is a commercial real-estate agent, and his line of work is actually fairly interesting. Although I don’t exactly see myself pursuing the exact same thing, I feel it would be helpful in the future to have background knowledge in real estate. 2. Ideally, five years from now I would like to be earning my Masters’ Degree in Finance. With this degree, the opportunitiesRead MoreImpact Of China s Economic Impact On Australian Property1364 Words   |  6 Pagescomes from china is the third largest group of Australia’s estimated resident population group (excluding people born in Australia). (Migration, 2015) as we know, ever since 1980s, China’s students flock into Australia to study. After they finished their study, quite a fair amount of them decide to get Australia’s PR or citizenship and stay in Australia. If people decide to stay, they need a place to live. So these students certainly brought huge impact to Australia’s real-estate industry. The impactRead More5 Cs Of B2b Lead Generation1195 Words   |  5 Pagesthe following ways: a) Prospect asking the sales person to send an introducing mail which describes about the company’s profile, credentials and achievements. The prospect might also give appointment at the first cold call (which is rare) or at the third or fourth call (which might take 3-4 weeks). b) Asks for company introduction mail and tells the sales person that he will let him/her know if there is an enquiry. c) In rarest of the rare cases the prospect gets so interested that he starts working

We Must Complete Co Ops - 884 Words

I will never cease to be amazed by how quickly I fall in love with ideas. I become completely consumed with a thought. I will go to New Zealand and work there and hike everyday, living out of a van with my best friend. I will attend Business school and love it and travel the world while doing so. I will go to Fiji, live on a rural island for four months teaching a class of ten year olds how to do long division. I have been lucky enough that all of the above things I have had to opportunity to do. Well. I am still in the process of business school and I might not say that I loooove it. It is pretty great though, you know, for university. And now my next thought. My next break through. I only found out about this idea 24 hours ago and I have been completely consumed with it for that entire time. In school we must complete co-ops; a great chance to try out careers to get some experience under your belt and they are paid. So it is exam time now which means procrastination is at an all time high. Lately when I procrastinate I look up potential careers for myself. It helps to motivate me, seeing a career that I would love to do that a business degree would be necessary for. It promotes the mindset that maybe I am doing the right thing spending ten thousand dollars a year on stress and books. I have a major travel bug and a huge passion for global volunteering so I always end up on their sites looking for positions. Let me tell you how much I wish I wanted to go into finance. ItShow MoreRelatedPlayer Modes Of Video Games1502 Words   |  7 Pagesways, but the way we play modern games has changed as well. Consider player modes. Player modes determine how a game will be played and is important to consider before purchasing a game. Many games are single-player only, and although almost any gamer has two or more controllers at home, it won t do any good to invite a friend to a game if the game developer deemed the player mode to be single-player only. The number of players for a game is a tell-tale sign of not only who we will play with,Read MoreCo Operative Education And Traditional Education1970 Words   |  8 Pagesaround us. We go to college or university to get educated. We entrust our children to schools in the belief that they will become knowledgeable and skilled† (Wood 11). Evidently, education is a long-term process, which almost all people must experience in life. So that, the choices associated with major, future job or kind of programs are controversial problems in general public, especially the issue of whether or not Co-operative (Co-op) education is better than traditional (Non Co-op) programs.Read MoreProject Clerk : My Role As A Management Engineer Essay1564 Words   |  7 Pagesas well as writing the draft copy. Moreover, I also assist to complete the Powerpoint and rubric. Nancy (Project Clerk): Throughout the project, my most prominent role was the secretary (mostly for milestone 4). For the first milestone, I created the Ishikawa, which outlined what kind of a tool the group wanted to created, why we want to make this, and how. Next in the second milestone, the team created a list of 8 functions we would like to implement in the tool. I was in charge of makingRead MoreTeam Collapse at RWH3340 Words   |  14 Pagesaudit would likely take a longer period of time to complete than the promised two and half weeks (the audit team completed the audit in this time frame in 2007) due to a) the expectation that extra work would be required related to possible asset and receivables write-downs as a result of the economic downturn; b) some accounting policies had been changed, which led to more time required from senior associates to help guide junior associates and co-op students through the company’s new set of circumstancesRead MoreWhat Is The Evalua tion Score Worksheet?1221 Words   |  5 PagesWe recommend scoring the applications in sessions, rather than one here and one there. You will find your sense of judgment more parallel among applications. You will also spend less time reorienting yourself. †¢ On the Evaluation Score Worksheet, enter the point value in the scoring system associated with the applicant’s cumulative GPA. †¢ There is no self-reported GPA, so dig for the cumulative GPA. All transcript formats differ, but it is generally easy to find. If you have a candidate from a schoolRead MoreWork Term Report3175 Words   |  13 PagesMBA Co-op Work Term Report Template Purpose: As one of the mandatory requirements of the MBA Co-op program, this report allows you to reflect on your past work term and provide information to other co-op students who are interested in working with your employer. Deadline: End of your work term / during the first week of class when you are back to campus Required: Must be reviewed and approved by your manager CBCD will accept any of the following as ‘approval’: †¢ Manager signed WorkRead MoreCase Analysis : V Auto Collection, Inc.1323 Words   |  6 PagesDarshana Bai Professor: John ward Case Analysis Assignment 09/19/2017 This case is Azte Inc. v Auto Collection, Inc., 2012 NY Slip Op 51731(Unpublished) [36 Misc. 3d 1238] (US Supreme Court, Kings County, 2012). The parties involved in this case were as follows: Plaintiff: AZTE, Inc. (AZTE), ABR Consulting Group Corp. (ABR), and Budget Autos LLC (Budget). Defendant: Steven Lever (Steven), Joshua Lever (Joshua, collectively the Levers), and Christopher Pinkow Witnesses for the complainant:Read More The Essence of Teamwork Essay1442 Words   |  6 Pagesadvancements in technology and a never before experienced contact between the western and eastern hemispheres of the world, there are new challenges that are being encountered now and will continue to be dealt with in the future. The challenges that must be met by today’s project teams are: Virtual Project Teaming, Cross-functional teams, Globalization, Diversity and Time to Market Pressure. Most of the common contributing factors to teamwork failure such as personality conflict, miscommunication orRead MoreSupplier Performance Essay727 Words   |  3 Pagesinto 5 categories: Service Level- number of lines shipped complete with recent addition of on time complete orders shipped. 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Science Limitations Free Essays

Science is a great way to learn and understand how our universe works. Once we learn science, we’re opened many new doors and can even learn how to manipulate our very own universe. Throughout the course of human events, science has helped mankind overcome a wide range of issues. We will write a custom essay sample on Science Limitations or any similar topic only for you Order Now However, science is a double-edged sword and has also brought many new issues. It is important to place limitations on science and research in order to prevent or abate anything that can go wrong during the ursuit of knowledge. The pursuit of knowledge can often blind one of potential problems that can arise during or after an experiment. â€Å"l collected the instruments of life around me, that I might infuse a spark of being into the lifeless thing that lay at my feet. † (Shelly 285) In Frankenstein, we can see that Victor becomes very elated to what he might infuse to his creation. However, he does not consider what might potentially go horribly wrong during this process. He doesn’t think anything can fail because the power to create something has shrouded his Judgment. It is for this very same reason why we have many energy and environment crises in our world today. Many scientists wish to help a company, themselves, or humanity and are engulfed by the end result that they become ignorant to any possible unwanted byproducts or results. Jeremy Rifkin also elaborates on the ignorance caused by the pursuit of knowledge in Biotech Century. Fears over the possibility of transgenic genes Jumping to wild weedy relatives heightened in 1996 when a Danish research team observed the transfer of such a gene – something critics of deliberate-release experiments have arned of for years and biotech companies have dismissed as a remote or nonexistent possibility. † (Rifkin 31 5) Rifkin explains that the transfer of genes from altered crops to weedy relativ es could create super weeds that are resilient to herbicide, pests, and viruses. These super weeds would cause farmers to spray even more herbicide on them. Naturally, this would affect our food supplies because we would be spraying so many harmful chemicals to the soil and to the food that eventually ends up at our dinner table. The companies and scientists seeking either onetary gain or any form of knowledge, deny any possibility of any deviations from their plans. Seeking to create plants that are resilient is a noble cause; however, ignoring the proven fact that it can also destroy the environment through the unintentional genesis of super weeds is another example of shrouded Judgment. The examples on ignorance, instigated by the pursuit of happiness, which Shelly and Rifkin elaborate upon, are clear reasons why there should be limitations imposed on scientists. Shelly also demonstrates how scientists meddle with nature and attempt to usurp nature’s role. l pursued nature to her hiding-places. † (Shelly 286) Victor was obsessed with the idea of having the power to create life. â€Å"†¦ listening attentively, demoniacal corpse to which I had so miserably given life. † (Shelly 289) Up until then, Victor was drunk with the idea that he was going to create the perfect specimen and the next evolution of man. Once Frankenstein was born, Victor was horrified that his plan to usurp nature had backfired. He realized Frankenstein was a â€Å"demoniacal corpse† and not human. This wasn’t a simple experiment where you could redo an experiment many times for a favorable result. Victor had created a monstrous living creature. He had introduced the living creature to an exotic environment, physically superior to others, intimidating in appearance, and predestined to be persecuted in a world where he had no idea why he was there. Rifkin also gives insight to the topic of scientist’s endeavor to usurp nature’s role. â€Å"In Just the past 18 months, genetically engineered corn, soy and cotton have been planted over millions of acres of U. S. farmland. Genetically engineered insects, fish and domesticated animals have also been introduced†¦ † (Rifkin 313) Companies are ntroducing thousands of new living specimens into real environments without a single thought of the real problems that could come out of these actions. Just like Victor, theyre caught up in the moment of having the power to create new life that has never even existed in nature prior to scientific advancements that allowed it. Consequentially, these new genetically engineered specimens can have disastrous effects on exotic environments that aren’t used to having them. They’re the modern Frankensteins. Rifkin appeals to the reader’s ethos by saying that, similar to Frankenstein, these enetically engineered creations are the works of man and are potential threats to any ecosystem they enter. â€Å"Genetically engineered products also reproduce. They grow and they migrate. (Rifkin 313) This means that the genetically engineered products of a lab can freely migrate themselves to any part of the world they can tolerate. Everyone is aware of the destruction brought by introducing exotic animals/ plants to ecosystems that are in harmony. Scientists are playing â€Å"ecological roulette† when they release these engineered creations because even if they were to admit or ind out that their creations had devastating effects, they would be unable â€Å"recall genetically engineered organisms back to the laboratory, especially those organisms that are microscopic in nature. (Rifkin 313) Rifkin and Shelly both make outstanding arguments on why there should be limitations on science where scientists dare not tread for the sake of order. They agree that the power to create life instills an ignorance that also gives birth to new sets of potential problems. Science will always be present in society because it holds a lot of prominence. Science is how we understand our universe and it allows us to hape it as well. Science has helped mankind out of the caves, increased the average life span, and also let us Journey to places where man could only dream of. Of course, like anything in this world, science will require a cost to advance. The cost can be in the form of problems that were nonexistent in nature before that sometimes do not outweigh the benefits. These same problems will also challenge our own humanity as well and our future on this planet. For these reasons, Rifkin, Shelly, and I believe that whilst science is a powerful force for the advancement of the human Is planet. How to cite Science Limitations, Papers

Accounting and Ethical Requirement-Free-Samples-Myassignmenthelp

Questions: 1.Prepare a letter of advice, for Jeffrey in relation to the procedural, accounting and ethical requirements he would have to meet to comply with the requirements under the Migration Act 1958. 2.What are your Obligations as a registered migration agent under the Code of Conduct? Answers: 1.Letter of Advice To Mr.________________ Address____________ Respected sir, We have applied for a Class UC subclass 457 visa that is granted for the temporary work in the continents of Australia. The visa will be granted by the Department of Immigration and Border Protection, Australia. You are appointed as a registered migration agent for completing the act. It is to be noted that being a registered agent in the migration sector, you should have to understand the basic principle of the Migration Act and the Regulations. Common principle of the migration law is applicable in Australia. The Migration Act 1958 and Migration Regulation Law 1994 in Australia regulate the migration law. There are certain provisions categorised in the Act and the Code of conducts that are deal with the validity of the visa of special class. In the present case, a problem arose regarding the 457 visa. It is a kind of visa that is provided to the employees who want to do temporary work in the Australia and this type of visa is common in the country. This type of visa arose in the period of John Howard, who was the Prime Minister of Australia. It became subclass 457 visa in the year of 2012. Department of Immigration and Border Protection are in the duty regarding the procedure of the visa. There are certain requirements are mentioned under the law regarding the applicability of the visa and being a registered agent, it is required you to know about the provision. The visa holder can work in Australia for a term of four years and he must have someone who has no restriction regarding the internal affairs of the country. The benefit regarding the visa holder is that he can go and come in that country as much as he can. There is no restriction regarding the travel of the visa holder but there is a limitation regarding his stay at the country. Another requirement is that the holder must have to take certain examination regarding the English language and the health requirements as well. There are certain restrictions applicable on the visa holder according to the provision of Migration Act 1958. Visa holder must have to engage in the workplace that is mentioned in the pre-nominated place. They must be associated with the work of their sponsors and they have to work for the days that are not less than 60 days. The Australian government has certain provision to review the application of the visa holder. These visas are granted for the temporary works and the limitations regarding the same is short term in nature. Certain criticism raised regarding the validity of the visa as certain situations are cropped up regarding the same. It has been noticed that most of the visa holders are not getting well paid by their sponsors and due to this there is a negative impression on the image of the visa are created. The initiatives taken by the government for ease the rules of the visa by excluding the language base requirements from the visa holding ground is also criticised. It should be notified that in case of granting the subclass visa (subclass 457), there is a need for explanation of certain procedural, and ethical requirements are to be done by the Migration agent. The term migration agent is an agent, who takes the responsibility regarding the procedural techniques of the visa holder and facilitates the proceedings. There is certain code of conducts that should be followed by the agent regarding their own job. However, it should be kept in mind that the provision of the code of conducts is applied only to the registered agents. Section 287 of the Migration Act 1958 has provided certain provisions regarding the same and it should be kept in mind that the agent must follow all the rules that are to be mentioned here. There are certain provision regarding the violation of the same has also been mentioned. In case of a breach is made or if the agent is alleged to violate the provision of the code of conduct, administrative proceeding can be taken agai nst him. The procedure can be taken place as per the provision of the Migration Act 1958 and the Migration Regulations 1994. If there is any misrepresentation regarding the same is done, the offender must have to face the criminal proceedings. It also attracts the provision of the Trade Practices Act 1974. However, there is no intention of the code to snatch away any duties that are imposed on the registered migration agent. The code is regulated by the Common law of Australia. Certain specific abilities are set out in the Code that must be abided by the agents. An agent should have certain professional qualifications that are to be pointed out by the Migration Act 1958. The agents should interact with the customers diligently. It is important to maintain the client list properly and deal with the customers fairly. There is a specific cost imposed for the granting of this visa. It may be varies if there is any person added in the visa. General fees regarding the visa are $420. The nomination fees are $330 and for the main applicant, the fees are $1,060. There are certain additional charges are applied on the visa and the amount is $700. The Migration Act has specified certain provisions regarding the procedural fairness of Migration Act. If there is any situation arises that, make the visa invalid, the ministers have power to cancel the same on the said ground. The provision relevant to the effect has been described under section 109. According to section 133, the minister can cancel the visa if there is a scope regarding the hamper of public interest takes place by the invalid visa. If the person who applies for the visa has not passed the qualification test, then the Ministry as per the provision of section 501A can cancel the same. In a case, where the person is alleged to have a past criminal record, the visa can be cancelled. Character test plays an important role regarding the issuance of visa for the temporary work. Under the provision mentioned in Section 501(3A), the ministry is conferred with the power to cancel the visa if the expected holder could not able to crack the necessary examination. Character test starts up by way of a police checking regarding the behaviour of the person. It is to be notified that whether the person was held for the criminal offence like child abuse or the sexual harassment. If any of the allegations be proved against the person, his visa will be cancelled. The procedure of cancellation is depending on the discretionary power of the Ministry, but no arbitrariness can be allowed and there must be certain specific reason shown by the Ministry. Ethical issues arose in the case where there is a dilemma regarding to come into a conclusion on the visa problem cropped up. In the case, certain ethical issues cropped up for the justification of the validity of the visa. There are certain provisions stated under the law of Migration that are specified under section 47 of the Migration Act 1958. In this letter of advice, the above noted provisions of the Code of conducts are being made for the better understanding of the same. It is yours duty to maintain a close relationship with the clients, as you are a registered agent. You are appointed as a registered agent for doing the job. You have demanded an amount of $3,800.00 as professional fees including GST and fees of disbursement. You have also asking for an amount of $1,500.00 to commence the work, which had been accepted by the Woods Engineering as an agent fees. The term disbursement denotes to pay certain money is paid for the cash expenditure that can raise the cash flow. In simple word, disbursements are paid by the company to do certain works. In this case, Wood Engineering promised to pay certain amount of money to Jeffrey for obtaining consent regarding the issuance of the visa by the respective authorities. Out of pocket expenses are the expenses that are to be spent without a possibility to get it back. Both of the terms are used to spend money for the fulfilment of certain work. In this case, the company wanted to disburse a certain amount to you regarding the subclass visa. The process of the visa by the agent is governed by the Migration Agent Regulation Act 1998 (MARA). There are certain provisions mentioned under the Code of Conduct for the migration agent. There are certain provisions mentioned under Migration Act 1958. It is a mandatory provision under the Migration Act that an agent must be registered. Therefore, these provisions are regulated the activities of migration agent. Concluding, I am sure that you will follow all the criteria regarding the issuance of subclass visa from the Department of Immigration and Border Protection and complete all the requirements as and when necessary. Regards, 2.There are certain provisions mentioned under the Migration Act 1958 that specifies the rules for the validity of a proper class of visa. In the present case, there is a case regarding the subclass visa are described. Generally, there are two sections that are deals with the requirements for the validity of the visas. A problem arises here in the case that the applicant told the migration agent that she had not paid fully for the visa and it was after four months of the lodging for the application. There are certain provisions mentioned in the Migration Act and in the Migration regulation that stated that all the procedures are needed to be met properly. Here in the case, a dilemma has been made in between the Jeffrey and the visa holder regarding the non-payment for the visa. The situation is attracted the provision of the code of conduct with an intention to deal with the problem. It has been mentioned under the code of conduct that every agent, who are registered under the Migration law, should be followed up certain rules that are specified under the code. The code has regulated the conducts or the ethics of the agents and there are certain grounds that are providing a full statement regarding the behaviour of the agent to the customer. It has been stated under the Code that the agent must act diligently with the customer and should not violate the provision of the Code and the Migration Act 1958. However, there is another situation cropped up here in the case. The applicant has confessed that she failed to meet the total amount of money payable for the visa and the company also knows the facts. There are various provisions mentioned under the code of conduct regarding the customer agent relationship and it has been stated that the agent must keep the confidential nature of the transaction if any and maintain a record regarding the financial criteria of the same. In the code of conduct there is a provision that stated that the agent should have certain information on the customers accounts and in case where a situation regarding the money has been cropped up, the agent has every right to disburse certain amount from the accounts of the customer. However, in such case, the agent must maintain all the necessary documents and should serve the customers a copy of it. The registered agent can keep an account to operate the expenses and if there is a necessity, the agent can disburse money from that account and send all necessary documents and copy of the same to the customers and the related company. All that is necessary for meeting the criteria is that the agent must fulfil all the requirements of the Migration Act 1958. He must act in good faith and maintain a good relationship with the customers. In certain situation, if there is a dilemma arose, the agent must take the assistance given in the Code of Conduct and should not violate the provisions of the same. Therefore, it can be stated that the registered agent should have to meet all the obligations mentioned in the Code of Conduct in case of dealing with the customers. Reference: Aleinikoff, T. Alexander, and Douglas Klusmeyer, eds. From migrants to citizens: Membership in a changing world. Institution Press, 2013Brookings. Baas, Michiel. "The Question of Racism: How to Understand the Violent Attacks on Indian Students in Australia?." Cosmopolitan Civil Societies: An Interdisciplinary Journal 7.3 (2015): 37-60. Breen, Fidelma. "Australian Immigration Policy in Practice: a case study of skill recognition and qualification transferability amongst Irish 457 visa holders." Australian Geographer 47.4 (2016): 491-509. Chen, Qi, et al. "Down-regulation of Gli transcription factor leads to the inhibition of migration and invasion of ovarian cancer cells via integrin 4-mediated FAK signaling." PloS one 9.2 (2014): e88386. Evans, Phil. "The building and construction industry code of conduct (WA)." Brief 44.6 (2017): 22. Fitzgerald, Jennifer, David Leblang, and Jessica C. Teets. "Defying the law of gravity: The political economy of international migration." World Politics 66.3 (2014): 406-445. Groutsis, Dimitria, Di van den Broek, and Will S. Harvey. "Transformations in network governance: the case of migration intermediaries." Journal of Ethnic and Migration Studies 41.10 (2015): 1558-1576. Murphy, Kerry. "Breaking down the 457 visa changes." Eureka Street 27.7 (2017): 8. Robertson, Shanthi. "Time and temporary migration: The case of temporary graduate workers and working holiday makers in Australia." Journal of Ethnic and Migration Studies 40.12 (2014): 1915-1933. Thornton, Simon, and Andrew Buckland. "Validity of immigration detention revisited." Litigation Notes 24 (2014): 19. Wright, Chris F. "Why do states adopt liberal immigration policies? The policymaking dynamics of skilled visa reform in Australia." Journal of Ethnic and Migration Studies 41.2 (2015): 306-328. Wright, Chris F., and Andreea Constantin. "An analysis of employers use of temporary skilled visas in Australia." Submission to the Senate Education and Employment References Committee Inquiry into the Impact of Australias Temporary Work Visa Programs on the Australian Labour Market and on the Temporary Work Visa Holders (2015). Yan, L., et al. "Regulation of tumor cell migration and invasion by the H19/let-7 axis is antagonized by metformin-induced DNA methylation." Oncogene 34.23 (2015): 3076. Zou, Mimi. "Immigration Law as Labour Market Regulation: Temporary Migration Status and Migrant Work Relations." Mondi migranti (2015).

25 Favorite Family History Quotes

25 Favorite Family History Quotes Are you looking for a quote related to genealogy and family history, for a family history photo or scrapbook, your Facebook or Twitter page, or a family genealogy website? These famous quotes include humorous quotes, inspirational quotes and other quotations related to our interest in the past. Why waste your money looking up your family tree? Just go into politics and your opponents will do it for you. -   Mark TwainIn all of us there is a hunger, marrow deep, to know our heritage - to know who we are and where we came from. Without this enriching knowledge, there is a hollow yearning. No matter what our attainments in life, there is still a vacuum, an emptiness, and the most disquieting loneliness. -   Alex Haley, RootsIf you would not be forgotten, as soon as you are dead and rotten; Either write things worthy of reading, or do things worthy of writing. -   Benjamin Franklin, May 1738There are only two lasting bequests we can give our children - one is roots, and the other, wings. -   Hodding S. CarterWhen a society or a civilization perishes, one condition can always be found. They forgot where they came from. -   Carle SandburgI dont know who my grandfather was, I am much more concerned to know what his grandson will be. -   Abraham LincolnYou live as long as you are remembered. -   Russian proverb Those who forget their past are destined to repeat it. -   Robert A. HeinleinWe are the children of many sires, and every drop of blood in us in its turn ... betrays its ancestor. -   Ralph Waldo EmersonEvery man  is a quotation from all his ancestors.  -   Ralph Waldo EmersonPeople will not look forward to posterity who never look backward to their ancestors. -   Edmund BurkeEveryone has ancestors and it is only a question of going back far enough to find a good one. -   Howard Kenneth NixonIt is a desirable thing to be well-descended, but the glory belongs to our ancestors. -   PlutarchAnybody can make history, only a great man can write it. -   He who has no fools, knaves, or beggars in his family was begot by a flash of lightning. -   Old English proverbIf you cannot get rid of the family skeleton, you may as well make it dance. -   George Bernard ShawThere is no king who has not had a slave among his ancestors, and no slave who has not had a king among his. -   Helen KellerFamily faces are magic mirrors. Looking at people who belong to us, we see the past, present and future. -   Gail Lumet Buckley Genealogy Tracing yourself back to people better than you are. -   John Garland PollardI dont have to look up my family tree because I know that Im the sap. -   Fred AllenIf you don’t know history, you don’t know anything. You are a leaf that doesn’t know it is part of a tree. - Michael CrichtonWe inherit from  our ancestors gifts so often taken for granted. Each of us contains within this inheritance of soul. We are links between the ages, containing past and present expectations, sacred memories and future promise. - Edward SellnerWeve uncovered some embarrassing ancestors in the not-too-distant past. Some horse thieves, and some people killed on Saturday nights. One of my relatives, unfortunately, was even in the newspaper business. -   Jimmy CarterA man who thinks too much about his ancestors is like a potato- the best part of him is underground - Henry S.F. CooperSoutherners are so devoted to genealogy that we see a family tree under every bush. -   Florence King

Early Infancy Benefits of the Toy Mobile

Early Infancy Benefits of the Toy Mobile During the first three months of life, an infant’s brain exhibits rapid development. The baby has a biological need to learn and absorb information from the outside world; it has a cognitive and a sensory need that requires nurturing at this stage of life ensuring that the rest of the stages in the baby’s life fall in their rightful places. Giving the baby stimulating experiences will help it to develop its brain and lay the foundation for more advanced learning later on as far as the baby’s sensory, biological and cognitive abilities are concerned.Advertising We will write a custom essay sample on Early Infancy: Benefits of the Toy Mobile specifically for you for only $16.05 $11/page Learn More The toy mobile is meant for a three-month old baby boy. The mobile toy is to be hanged in the crib as the child cannot yet sit upright by itself. It is small in size to enable the child to easily reach all its corners. Different toys have differe nt shapes and colors. The toy mobile is bright-colored with soft keys that have different textures due to the fabrics used-muslin with a square shape. Additionally, the toy mobile has high-contrast patterns. Infants have a tendency of putting all objects within their reach in their mouths. The ideal size of the toys will be significantly big to ensure that the child does not get into his/her mouth. The toys are all dangling back and forth in a steady speed. In addition to the dangling aspect, the toy mobile has fixtures that enable it to make soft and audible noises. The sounds are musical, some of which having a high tempo while others are rather slow and soothing. For some of the toys, the sounds are triggered by pressing certain buttons/keys while for the rest of the toys sounds are produced by pushing some attachments on the toy. On pressing the toy mobile’s key, lights of different shades are produced. The mobile toy has the ability to make accidental squeaks once presse d. The child can bat, pull, spin and rattle the toys with ease. The toy mobile is sweet-scented with a yummy taste and has an unbreakable mirror. It also has an activity mat of soft texture. Additionally, it has many convenient features including removable music box, adjustable swivel arm, and push button power. In the manufacture of the toy mobile, a lot has been taken into consideration as far as cognitive, sensory and biological abilities are concerned because every now and then, infants who are less than eight months old are always thinking, learning and exploring the world around them. They are always discovering new things in their environment. Their age is the age of wonder where the baby is focusing on moving things. The baby can only see clearly within a distance of around fifteen inches. The baby is in a position to see all colors in the human spectrum and is able to respond to the environment with facial expressions and imitate them. The ability to tell sweet from sour is already built up and the baby can react to familiar sounds. The baby uses their mouths and hands to explore which too has been factored in designing the toy mobile.Advertising Looking for essay on anthropology? Let's see if we can help you! Get your first paper with 15% OFF Learn More The design of the toy mobile provides features that match the sensory, cognitive and biological abilities of an infant. It has multiple attachments each catering for different abilities concerning the above mentioned. The toy mobile is hanged on a baby crib which provides the infant with a point to focus on during the time they spend in the crib. For the stimulation of the infant’s sense of sight, the different shapes as well as the different shades of the toy serve the purpose because the child can see at this age and make out different moves up, down and even when someone passes by him/her. The toy mobile is around fifteen inches away from the child because the child c an see that far. At the age of three months, the baby’s visual ability is limited since they can only see objects within a fifteen inches diameter as afore mentioned, which is why, the mobile toy is hung at such a level that the baby will not see blurred images and items. The soft keys or rather key pads help in the development of the infant’s sense of touch. Owing to this fact different fabrics are chosen to provide the soft and smooth texture of the toy. At this age, the baby has opened his fist and almost every now and then, it plays with the feet using the opened fist in a grabbing manner. Hard fabrics will scare the child away from holding things because the child’s hand has just opened up to grasp things and thus it’s very soft and tender thus the muslin square material serves the purpose. This stimulates touch and increases the child’s alertness and attention span. The toy mobile has dangling toys that dangle in such a manner that the child is made to lift its head and chest as if doing some push-ups. This contributes to the active behavior of the child and enhances its back’s strength. Additionally, the dangling makes strengthen the child’s neck. While dangling, the toys rattle making some noise that the child responds to by laughing or cooing. Moreover, the toys are made of small sizes to ensure that the baby can hold them, an aspect that enhances the development of the muscles within the infant’s hand. The smaller the size of the toys, the easier and faster the child’s hand will develop as far as holding is concerned. The child at this age is changing toys from one hand to another. The mobile toy has multiple features that are close for the baby to grab with ease and comfort. This action enhances the child’s cognitive ability to pass objects from one hand to the. Furthermore, being able to reach for the toys will enhance coordination skills in the child that add up to cognitive abi lities.Advertising We will write a custom essay sample on Early Infancy: Benefits of the Toy Mobile specifically for you for only $16.05 $11/page Learn More The child at this age is making some funny noises and thus for verbal stimulation, the toy is able to make some sensible noise which aids in the child’s development. The accidental squeaks will help the child become more aware of what the hand is doing. Additionally, the ability of the toy to play different tunes of music enables the child to become more vocal. The music needs to be played from time to time with different tunes for the baby to useful acquire and learn different tunes. The mobile’s position should be changed from time to time to allow the baby to get a new view and sharpen its memory when trying to locate moving. This is made possible by the fact that it has an adjustable swiveled arm. The toy mobile has some soothers that help the child a lot as far as sleep is concerned. It can also be used to regulate the infant’s behavior. For instance, when the soother plays some gentle music on a repeatedly slow tune, the child goes to sleep. This makes it possible for the sleep patterns to be monitored. When it is time for the baby to sleep, using the toy mobile can ease the caretaker’s task. In enhancing the child’s ability to focus, the baby sitter can point at the different lights produced by the toy. This in return enhances the child’s visual ability as well as the child’s memory. Switching through the music and finding one that soothes, helps the child learn and adapt to the music for sleep. With this, the child can easily adapt to the outside environment. The squeaking sounds sharpen the child’s hearing ability and the child will follow sounds made from different directions in the toy mobile. Colors and high-contrast patterns are a great way to stimulate the babys visual sense. Bright colors are easily visible and that is why the toy mobile is made of bright colors that enhance sight ability. Additionally, the sweet scent in the crib boosts the smell sensory skill. The yummy taste boosts the child’s ability to the sense of taste. Additionally, the size of the toys plays a very critical role when it comes to taste because the child will grab a toy and take it straight to its mouth and if very small, it will be swallowed harming the baby. Babies prefer viewing human faces and this makes him laugh with them. The mirror gives the child the impression that there is someone teasing him/her for at this age the child cannot know that he is the same in the mirror. This boosts visibility and the memory in return. The activity mat laid on the crib for the baby to sit on helps the baby during the tummy time where the baby lifts and tries to lift its legs. This boosts its fine motor skills. The texture of the mat is very useful in preventing bruising of the baby while doing the semi push-ups while lying on its tummy.Advertising Looking for essay on anthropology? Let's see if we can help you! Get your first paper with 15% OFF Learn More In essence, the toy mobile manufactured helps the child a great deal during its growth. The skills to taste, see, hear, smell and touch have been taken care of by the music, the bright colors and contrast pattern, the scented crib, the soft toys among other characteristics of the toy mobile. This makes it easier for the child to move to the next level with enthusiasm and great fitness. The toy enhances the development of the child in all ways possible. In conclusion, the toy mobile manufactured is a blessing to the mother and the child as well. The benefits it accrues them both are immeasurable. It stimulates the infants sensory, biological and cognitive abilities as discussed above. The nervous system, as a major concern, is developed by the fact that the toy mobile allows the child to move from one state to another with ease. Giving the baby stimulating experiences will help it to develop its brain and lay the foundation for more advanced learning later on as far as the babyâ€⠄¢s sensory, biological and cognitive abilities are concerned. Once one stage of life is well and healthy, the next one becomes easier to undertake. Thus, the three month old baby grows healthy courtesy of the toy mobile.

How do Piagets and Vygotskys theories of learning and development Essay

How do Piagets and Vygotskys theories of learning and development compare regarding the influences of social interactions in childrens cognitive development - Essay Example These theories include Maturationist, Environmentalist and Constructivists ones. These three schools of thoughts have different views and ideas on child development. Piaget and Vygotsky are the pioneers and representatives of the Constructivist school of thought. Both of them have similarities and dissimilarities in their views. Before discussing the three aspects of child development, it is necessary to define cognitive psychology. In the words of Anderson: Cognitive psychology attempts to understand the nature of human intelligence and how people think. The study of cognitive psychology is motivated by scientific curiosity, by the desire for practical applications, and by the need to provide a foundation for other fields of social science. (Anderson, 1990:1) The Swiss biologist Jean Piaget and Russian psychologist Lev Semyonovich Vygotsky were the theorists to advance the constructivist theory of Cognitive development in children. According to which the cognitive development starts in children with their interaction with the environment and people around them. It is necessary for a child’s development, according to them, that he must interact with other individuals of society. The theory is different from the Maturationist school of thought. The Maturationist theorists believe that the cognitive development is a biological process, and all the healthy (normal) children get it as long as they grow physically. The theorists including Arnold Gessel and others believe that the cognitive development occur naturally and automatically. DeCos has quoted their views in these words: School readiness, according to maturationists, is a state at which all healthy young children arrive when they can perform tasks such as reciting the alphabet and counting; these tasks are required for learning more complex tasks such as reading and arithmetic. (DeCos, 1997) On the other hand, constructivists are of the view that development in children is not the outcome of

Ford Case (Marketing) Analysis Essay Example | Topics and Well Written Essays - 1250 words

Ford Case (Marketing) Analysis - Essay Example However, according to Sullivan-Diaz, her father was never interested in services part of the business and it was only a necessary adjunct of the business. The problem starts right from here because Sullivan family has been unable to identify the strong interdependency between product sales and services. Nowadays, marketing products and services are interdependent because of the changing consumers’ buying behaviour. Consumers make the purchase after considering how the services later on, will benefit them. However, at Auto World, a huge difference has been noticed between their efforts to market products and providing services. First, the showroom was built in modern building with latest facilities and ambient whereas, the services section was hidden behind the showroom and its building was old and greasy however, the equipment was latest. Second, services section had sufficient capacity to handle more repair work but the capacity was not being achieved because of the requirements of more mechanics and more focus of the staff towards unit sales. The major difference between marketing products and service operations is that services require the personal contact or face-face meeting. At Auto World, the buyers of new cars were given a warm welcome however, whenever the same customer came for car services, he used to wait for many hours. The major reason is that marketing cars was being considered to be a highly efficient process whereas, service operations were very inefficient and even the service layout was not properly developed. Auto World is offering tangible products and services to the customers, and both these components are contributing to create value for the customers. Therefore, company should give great focus towards both marketing cars and services operations. If the company has been able to introduce used cars after ensuring their full repair and maintenance, then it should be also efficient in its services operations.

International banking law Essay Example | Topics and Well Written Essays - 3750 words

International banking law - Essay Example The objective of the Basel Committee’s reform package is to improve the banking sector’s ability to absorb shocks arising from financial and economic stress, whatever the source, thus reducing the risk of spill over from the financial sector to the real economy (Basel Committee on Banking Supervision, 2009). This paper shall present a critical analysis of the proposals and finally make a determination of its efficacy, practicability and compliance amongst the banking sector around the world. The repeated and continuing onslaught of economic stressors starting from the past decade has left the banking industry more fragile. The Basel Committee on Banking Supervision has long recognized its role in providing guidance not only to banks but also to regulators to ensure that the banking system remains not only resilient in the face of economic slowdown or down turn but also to be more prudent in their fiscal management. The viability of the Basel Committee’s previous recommendations and proposal was regarded as the cure for the ailing global banking industry however, Basel III’s round of proposal are too complex (Allen, Chan, Milne, & Thomas, 2010) BASEL III Proposals Emerging from the three pillars of Basel II that would include (1) risk management; (2) regulatory governance; and (3) corporate governance that aims to ensure the risk sensitivity of capital allocation, quantification and separation of operational risk and credit risk, and lastly to align regulatory arbitrage. Basel III has the following proposal that aim to strengthen the international Banking industry further. 1. Capital Base Learning from its experiences in the past, the banking industry which have faced several global financial crisis have determined that the capital base of some banks are of insufficient quality. Normally these are the banks that are considered as the ground zero of the financial crisis. These banks are then forced to rebuild their capital base at a ti me when it is hard to do so. Governments are then forced to intervene that may save the situation temporarily however the domino effect of the whole financial industry will just make matters worse (Basel Committee on Banking Supervision, 2009). A key element and rationale of this proposal is that common equity is still regarded as the highest quality component of capital due to its peculiar nature of absorbing losses when they occur, full flexibility of dividend payments and lastly it has no maturity date. It makes sense to use it as an instrument to ensure a bank’s liquidity. The proposal also emphasize that the creative way of firming up capital with non-common equity to meet regulatory requirement should be limited. However, regulators should also take into consideration another form of high quality equity that can be converted into common equity these are equity coming from mutual funds and cooperatives. Responding to the growing concern on security the proposal also stre ssed the need for full disclosure of the nature of capitalization. Capitalization Tier 1 capitalization refers to the actual common equity of a bank. In the current practice equity can be in a form of bond, stocks, tradable financial paper and other similar instruments. The very nature of the tradable instruments is the variability of its value. BASEL III has

Prosthetic Rehabilitation of a Patient with Nose Defect

Prosthetic Rehabilitation of a Patient with Nose Defect Case Report Authors: Satyabodh S Guttal, MDS,MFPT 1, Blessy Bangera, BDS,2 Adarsh Kudva,  MDS,3 Basavaraj R Patil, MS, 4 Abstract Midfacial defects are enormous defects that result from cancer treatment that rarely are corrected by surgical reconstruction alone; they generally require a facial prosthesis to restore function and appearance. Surgical reconstruction may be viable for few defects, which are done with different flaps. But for the total nasal resection, prosthetic option would be more feasible. Nasal cartilaginous anatomy is complex due to the varying contours. Therefore it may be difficult for the surgeon to reconstruct the entire nose. This clinical report describes the rehabilitation of a large midfacial nose defect with a dental implant retained nasal prosthesis. The patient had adenocystic carcinoma of the medial maxillary wall extending to the nose. Introduction The face being the most noticeable part of the body when disfigured may lead to an impaired social life stemming from esthetic problems. 1, 2 Among facial defects, nasal defects produce severe cosmetic impairment. . Rehabilitation of such defects subsequent to surgery is done in a sequential manner, which includes a surgical, provisional, and definitive prosthesis. 3 Prosthesis helps restore the patients self-esteem and confidence, hence affecting the patients and their life style. 4-6 Adenoid cystic carcinoma (ACC) is a rare malignant perineural tumour of the major and minor salivary glands, accounting for 2% of all head and neck malignancies and approximately 10% of all salivary gland neoplasms. 60% to 70% of ACC’s arise in the minor salivary glands, which may be localized in the palate, paranasal sinuses and nose, although they may also occur in the parotid or submandibular glands.7 In the past, nasal prostheses were held in position with strings or straps fastened behind the head,8 intranasal or intraoral extensions,9,10 and gold strings or leaves.11-13 Spectacle frames have been accepted for securing nasal prostheses.14,15 Today, with the development of biomaterials, prosthetic substitutes are secured with readily available adhesives that are effortlessly applied 16 however, the effectiveness of adhesives is questionable considering presence of mobile tissues in the defect, nasal secretions, and moist air associated with respiration.17 These factors would compromise the adhesiveness. The concept of osseointegration 18 has enabled a more reliable mode of retaining nasal prostheses. 19 This clinical report describes the rehabilitation of a large midfacial defect using an implant retained nasal prosthesis. Clinical Report: A 63-year-old female patient who reported to the B.R Patil Cancer hospital, Navanagar, Dharwad was diagnosed with adenocystic carcinoma of the medial maxillary wall. Patient had no medical co-morbidity. Patient gave history of nasal obstruction due to nasal mass on left side of the nostril for which medial maxillectomy was done via endoscopic approach in the year 1993. Then in 2012 she reported back with the complaint of nodular swelling over nasal dorsum with tearing and nasal obstruction with no orbital symptoms. Intra-orally patient had destruction of palate on the left side crossing midline. Upon further investigation, biopsy revealed adenocystic carcinoma of the nose and left maxilla with no involvement of orbit or anterior skull base (Fig 1). Two cycles of chemotherapy with cisplatin, 5 flurouracil and paclitaxel according to body surface area was given. The defect resulting after excision had to be covered at the earliest. Hence, prior to surgical intervention, prosthetic consultation was suggested to the patient who was thus referred to our Department of Maxillofacial Prosthodontics. Since an immediate definitive prosthesis was not feasible, the patient was suggested for temporary rehabilitation with an interim silicone nasal prosthesis with an attached eyeglass frame. However, since the patient expressed her displeasure towards spectacles for lifelong usage, she was given the option of implant-retained definitive silicone nose prosthesis. The patient agreed for the same. An orthopantomograph and computerized tomography scan were made as a part of the investigation to evaluate the bone height for implant placement. Left total maxillectomy with palatal resection across midline and total nasal resection done via weber ferguson incision, left modified radical neck dissection type three via macfee incision was made. The glabellar bone was evaluated on the operation table and upon conclusion that adequate bone was available; a single implant of 4.2 diameter x 6.5mm length, (Toureg S; Adin implants, Nazareth, Israel) was placed (Fig 2). The advantage of placing the implant on the operation table was that the patient would be under general anesthesia, and the psychological trauma of undergoing another surgical procedure was avoided. Following a healing period of 3 months the open tray impression posts were placed and the final impression was made. The abutment was placed on the implant and a custom made acrylic sleeve was fabricated for the abutment (Fig 3). A wax sculpted nose on the master cast was made to adapt to the margins of the healing wound. On either sides of the acrylic resin sleeve, two neodymium-iron-boron magnets, 5mm diameter x 1.2mm thick (Magnatech; Mumbai, India) were embedded into extensions made out of autopolymerising resin. The structure hence resembled a winged sleeve which was cemented on to the abutment using zinc-phosphate cement (Harvard Dental, Hoppegarten,Germany) (Fig 4). An acrylic resin index was fabricated over this structure which would harbor the respective magnetic keepers. The acrylic index was placed at its position over the magnets and was picked up by the wax nose that was placed on it using a drop of cyanoacrylate. The resulting wax nose thus incorporated an acrylic index with the magnetic keepers. This wax nose was carefully invested and the packing procedure using silicone and acrylic resin border framework, intrinsic coloring was carried out as mentioned for the interim above. Extrinsic coloring and pigmentation was done and patient was happy with the esthetic results. Digital weighing scale revealed that the definitive nasal prosthesis weighed around 12.2gms. The retentive force offered by the two neodymium-iron-boron magnets (Magnatech; Mumbai, India) was found to be 7.2N. The prosthesis was delivered to the patient (Fig 56). Following this, home-care instructions were given. In the subjective evaluation, the patient was very happy with the esthetics outcome of the prosthesis and expressed her great pleasure towards her ability to swallow liquids. The ryles tube continued to remain in place considering the general health condition of the patient and the need to feed semi solid food and protein supplements. The prosthesis was light in weight and could be comfortably placed in position as it was self-aligning due to the use of magnets. Patient, who is now on regular periodic follow-up ie, recalling at every 3 month period, is found to be doing well. Discussion Nasal reconstruction modalities comprises of primary closure, healing by secondary intention, skin grafts and local flaps and regional flaps. Small surgical defects can be treated well with different types of local flaps. The forehead flap is the better option for the large nasal defects. 20 The complex anatomical configuration may cause difficulty in surgical rehabilitation. In such cases, prosthetic closure is predictable and hence usually the treatment of choice. 21,22 The breakthrough for rehabilitation of facial defects with implant-retained prostheses came with the development of the modern silicones and bone anchorage. The limitations of the prosthesis were explained to the patient prior to the treatment, that fact that the prosthesis would enhance esthetics but would contribute less to the functions like speech and masticatory habits. Hence, the patient had no psychological set back on the prognosis of the treatment. In addition, there was a major set-back in terms of achieving outstanding esthetical and functional outcome due to the fact that all the work was carried out under technical constraints. This included a lack of time, chair-side patient availability, and ideal light conditions which, to an extent precluded optimal color blending. The main objective of treating this case was to close the open defect, to prevent the further spread of infection in the soft tissues exposed to the environment. The use of a magnetic assembly has eliminated the need for use of spectacle retention as per the patient’s request. The patient indicated that the nasal prosthesis reduced self-consciousness and was comfortable to wear without any type of irritation to the surrounding skin. The patient was pleased with her appearance and no longer found the need to wrap a cloth around her face. References Guttal SS, Patil NP, Thakur S, Kumar MV, Kulkarni S. Implant-Retained Nasal Prosthesis for a Patient Following Partial Rhinectomy: A Clinical Report . J Prosthodont 2009; 18:353–8. Kumar S, Rajtilak G, Rajasekar V, Kumar M. Nasal prosthesis for a patient with xeroderma pigmentosum. J Pharm Bioallied Sci 2013; 5:176-8. Marunick MT, Harrison R, Beumer J. Prosthodontic rehabilitation of midfacial defects. J Prosthet Dent 1985; 54:553-60. Buzayan MM. Prosthetic management of mid-facial defect with magnet-retained silicone prosthesis. Prosthet Orthot Int 2014; 38:62-7. Jain S, Maru K, Shukla J, Vyas A, Pillai R, Jain P. Nasal prosthesis rehabilitation: a case report. J Indian Prosthodont Soc 2011; 11:265-9. Anantharaju A, Kamath G, Mody P, Nooji D. Prosthetic rehabilitation of Oro-nasal defect. J Indian Prosthodont Soc 2011; 11:242-5. Shimamoto H, Chindasombatjaroen J, Kakimoto N, Kishino M, Murakami S, Furukawa S. Perineural spread of adenoid cystic carcinoma in the oral and maxillofacial regions: evaluation with contrast-enhanced CT and MRI. Dentomaxillofac Radiol 2012; 41:143–51. Saunders RCH. The gunner with the silver mask. Am Med Hist 1941; 3:283-5. Kazanjian VH, Rowe AT, Young HA. Prosthesis of the mouth and face. J Dent Res 1932;12:1 Kazanjian VH. Treatment of nasal deformities. J Am Med Assoc 1925; 84:177. Bulbulian AH. Facial Prosthetics. Springfield IL, US, Ed 1, 1973 pp. 364-7. Baird WH. An artificial nose. Dent Cosmos 1905; 47:560. Baker L. An artificial nose and palate. Dent Cosmos 1905; 47: 561. Rodrigues S, Shenoy VK, Shenoy K. Prosthetic rehabilitation of a patient after partial rhinectomy: a clinical report. J Prosthet Dent 2005; 93:125-8. Guttal SS, Patil NP, Shetye AD. Prosthetic rehabilitation of a midfacial defect resulting from lethal midline granuloma: a clinical report. J Oral Rehabil 2006; 33:863-7. Parel SM. Diminishing dependence on adhesive for retention of facial prosthesis. J Prosthet Dent 1980;43:552-60. Parel SM, Branemark PI, Tjellstrom A, Gion G. Osseointegration in maxillofacial prosthetics. Part II: extraoral applications. J Prosthet Dent 1986;55:600-6. Brà ¥nemark PI, Adell R, Breine U, Hansson BO, Lindstrà ¶m J, Ohlsson A. Intra-osseous anchorage of dental prostheses. I. Experimental studies. Scand J Plast Reconstr Surg 1969;3:81-100. Nishimura RD, Roumanas E, Moy PK, Sugai T. Nasal defects and osseointegrated implants: UCLA experience. J Prosthet Dent 1996;76:597-02. Kose R, Okur MI. Reconstruction of the defects in the middle of the nose with subcutaneous pedicled nasolabial island flap: report of two cases. Kulak Burun Bogaz Ihtis Derg. 2009;19(5):272-276 Sashi Purna CR, Annapurna PD, Ahmed SB, Vurla S, Nalla S, Abhishek SM. Two-piece nasal septum prosthesis for a large nasal septum perforation: a clinical report. J Prosthodont 2013;22:143-7. Goveas R, Puttipisitchet O, Shrestha B, Thaworanunta S, Srithavaj ML. Silicone nasal prosthesis retained by an intranasal stent: a clinical report. J Prosthet Dent 2012;108:129-32. Figure Legends: Fig 1: Preoperative patients photograph Fig 2: Placement of titanium dental implant in the glabella,-confirmed on the x-ray. Fig 3: Abutment threaded to implant and the trial of acrylic resin sleeve done. Fig 4: Cemented acrylic resin framework embedded with magnets on either side. Fig 5: Comparison between before and after prosthesis placement. Fig 6: Lateral profile of before and after prosthesis placement. Spectacle glasses were given to camouflage the borders of the prosthesis.

Wordsworth and Vaughan Essay -- Poetry Wordsworth Vaughan Essays

Wordsworth and Vaughan When reading T.S. Eliot’s critical comment, â€Å"It is to be observed that the language of these poets is as a rule simple and pure,† one might assume that he was referring to the Romantics (Eliot 2328). Specifically, we could apply this statement to poets the ilk of Wordsworth, who eschewed poetic affectations and â€Å"tricked out† language for sentiments that originated and flowed naturally (Wordsworth 270). Yet Eliot hadn’t focused his critical eye there, this time. Rather, he squinted a century back to a lesser-referenced literary group, the Metaphysical poets (Eliot 2328). That the Metaphysical poets and the Romantics share a characteristically simple/natural diction is important. While they are undoubtedly distinct schools, if we can show that they are even remotely stylistically similar, then we might have grounds to acknowledge similarities between a poet from each, respectively. Thus, I propose considering Wordsworth in relation to an earl ier man, Henry Vaughan. I am not the first to do so; much has been said of the link between these men regarding their analogous poems â€Å"The Retreat† and â€Å"Ode: Intimations of Immortality†Ã¢â‚¬â€by comparing them I cannot claim any original insight. However, there is more common to these two men than two poems, and in analyzing what Wordsworth desires from poetry and the poet in his â€Å"Preface to the Lyrical Ballads† we see that Vaughan had many of the poetic qualities Wordsworth demanded of himself. Even more interesting, Wordsworth's shifted perspective from â€Å"Lines Composed a Few Miles Above Tintern Abbey† to the "Elegiac Stanza" replicates Vaughan's shift from "To Amoret" to "The Night." Where Vaughan’s verse originally addressed worldly love and natural ... ...h happiness, wherever it be known, / Is to be pitied; for ‘tis surely blind† (lines 53-56). In these lines, Wordsworth finally counsels that the human world is actually not so near-sighted. Rather, when a man assumes himself separate from mankind—when he reinforces that separation—he actually blinds himself. So finally, the comparison between Vaughan and Wordsworth is not absolute. However, sorting through the words of men who’ve been dead for centuries for evidence of a literary association beyond mere coincidence is never and easy undertaking. But let us assume that, if Wordsworth was right, both he and Vaughan shared universal human experiences. Perhaps, upon reaching a certain middle age, they also shared fear and awe of the conditions of their mortality—and if one may have looked to the other’s words for poetic guidance, the poetic genre is better for it.

Professional relationships with children Essay

1.1 Describe how to establish respectful, professional relationships with children any young people To establish and maintain a respectful and professional relationship with children and young people in setting the Teaching assistant must always put the children first, never appear bored or uninterested, always encourage children and never make them feel like they have said something silly as this may make them reluctant to join in class discussion or turn to the teaching assistant for help. Body language is very important, if a child senses anger or unrest this may make the child not want to approach the TA with any problems or concerns they may have. The TA must always maintain eye contact and be friendly and approachable; they must also remember to give short and clear instructions to the children as they can only process it a bit at a time. If the TA has children or friend’s children within the school they must not discuss any child with any parent and their friends must be made aware that if they require any information on their child they must speak directly to the teacher. 1.2 Describe with examples how to behave appropriately for a child or young person’s stage of development Children and young people are still developing their language skills so it is important that the TA uses the correct terminology when in the classroom, in the key stage one they are learning phonics and it is important that the TA uses the same pronunciation as the teachers as this will confuse the children. The TA must never use inappropriate language i.e. swearing or slang words as this is not setting a good example to the children. When in setting the TA must dress appropriately no low cut tops. This can be very distracting. The TA must give the children their full attentions and not be distracted as they will pick up on this and it can impact negatively on the children and they will be reluctant to be involved with the TA. The TA needs to set a good example and be a good role model. 1.3 Describe how to deal with disagreements between children and young people Children and young people often have disagreements and fall out amongst themselves due to differences of opinion or personality clashes, it is important to stay calm and try to diffuse the situation, make sure that  both sides of the story are heard be fair and do not take sides. If the TA is unsure of anything then they must seek help from colleagues. 1.4 Describe how your own behaviour could: – Promote effective interactions with children and young people In setting body language is the first thing a child notices about the TA. Children can tell when there is something wrong. It can be off putting for a child if they are worrying whether they have upset the TA or not. If you are smiling they are smiling they can also tell when it’s not a genuine smile too, so never try to force one. -Impact negatively on interactions with children and young people Again a child can tell if you are genuinely in a good mood or not, if they are picking up on the TAs mood then it can impact hugely in a negative way as they might not want help form the TA and this could put them behind with their work and get them into trouble with the teacher. Adults 2.1 Describe how to establish respectful, professional relationships with adults In setting it is important to establish a good professional working relationship with adult’s weather it is a teacher or a parent. The TA needs to be respectful of other people’s views and opinions even if it differs from theirs. It is also important to be polite as the TA is not only to help the teachers but to set a good example to the children. 2.2 Describe the importance of adult relationships as role models for children and young people If the children see a good working relationship between adults then they are more likely to give other children the same courtesy. If the child sees politeness and good manners they are more likely to do the same. If is important for the adults to set a good example to the children. Communicating with children, young people and adults in an educational environment is an important part of a professional relationship 3.1 Describe how communication with children and young people differs across different age ranges and stages of development When communicating with babies and toddlers parents often use baby language I.e. choo choo for train and woof woof for dogs but this will not help them later on when the time comes to go to school, as they grow the need to be taught the proper words for things as it will make it more difficult when they start school and it will confuse them. In early years at school they concentrate on phonics, numeracy and  literacy this helps them develop their language and mathematical skills and helps them for the rest of their school life. Each child has a different way of learning. The TA must be able to communicate with each child regardless of their learning abilities. Communication can differ among different ages and stages as the younger children may have difficulties such as speech problems which in older children this may have already been addressed. 3.2 Describe the main differences between communicating with adults and communicating with children and young people The difference between communicating with adults, children and young people are adults are able to process information much more quickly and effectively than small children and young people. When speaking to small children and young people you must use precise instructions so they understand what you want them to do. When speaking to adults sometimes we use sarcasm but small children and young people do not understand sarcasm and they may take it as the TA being nasty. Sometimes we have to raise our voices to be heard or to get our point across but when dealing with children that is not always the best way, if you want them to do something it is better to ask them calmly rather than shouting. 3.3 Examples of communication difficulties – Speech – Hearing – Language/different accents – Disability – Social Issues – Emotional Issues – Lack of stimulation – Lack of concentration – Lack of time – Abuse/neglect – Environment – Religion – Quiet/shy – Autism 3.4 Describe how to adapt communication to meet different communication needs In everyday life there are communication difficulties and it is the same at  school, there can be language barriers or hearing problems you just need to be able to adapt learning around there issues for example writing things down, written instruction or speaking slower more clearly, misunderstandings happen more often than not when a child has misunderstood instruction, do not rush a child if they feel under pressure they are more likely to get it wrong. Also respect others views and opinions even if you do not agree. 3.5 Describe how to deal with disagreements between: – The practitioner and children and young people If there are disagreements between a child and a TA the TA must involve another member of staff who can remain objective and not take sides as with all disagreements both parties should be treated fairly. The TA must not shout and behave inappropriately as this does not set a good example. * The practitioner and other adults If there are disagreements in setting between the TA and another adult it is important to try and resolve the situation as quickly and as calmly as possible to maintain relationships, if there are unresolved issues then the school grievance policy should be followed. Underpinning communication and professional relationships is the principle of confidentiality 4.1 Identify relevant legal requirements and procedures covering confidentiality, data protection and the disclosure of information The Data Protection act 1998 requires that information is – Accurate and relevant – Kept secure – Obtained and processed fairly and lawfully – Processed for limited purposes and not in any manner incompatible with those purposes -Held for no longer than necessary -Only disclosed if specific conditions set out in the act are satisfied 4.2 Describe the importance of reassuring children, young people and adults of the confidentiality of shared information and the limits of this It is of the utmost importance that children, young people and adults are reassured of the confidentiality of shared information as if they feel that what they tell people is going to become common knowledge then they will be reluctant  to tell anyone, this could lead to things been missed and someone getting hurt. Children, young people and adults need to be aware that things will remain confidential within reason, sometimes confidentialities have to be broken if someone ids in immediate danger or there are reports of abuse. 4.3 Identify the kinds of situations when confidentiality protocols must be breached – Sexual abuse – Physical abuse – Neglect -Self harm Resubmission TDA 2.3 Communication and Professional relationships with children, young people and adults 1.3 Describe how to deal with disagreements between children and young people When in setting if I was in that situation I would seek help from another member of staff so that the child or young person could be heard fairly as it is important that both sides of the story are heard. Both parties must be treated equally until the situation is resolved. I would need to remain calm and try to diffuse the situation without shouting. 1.4 Describe how your own behaviour could promote effective interactions with children and young people When dealing with children and young people the TA must be friendly, approachable, give praise where needed and support the children with their work and make them feel valued and that their opinion counts. This can have a very positive impact on the children, their work can improve and their self-confidence will improve. If a child or young person doesn’t feel that they or their opinions matter the will not progress properly and this can impact negatively on their education. They will not want to show their work or may feel silly asking questions, it is a TA’s job to help support the children and young people and make them feel valued. 2.1 Describe how to establish a respectful professional relationship with adults It is important to establish a respectful professional relationship in setting because we are there to set a good example to the children and young people and if they see adults behaving or speaking inappropriately then they will think it is acceptable to do the same, we are there to be good role models. It is also important to establish a good professional relationship with the parents whether they are your friends or not as they must understand that there are  rules and the TA’s cannot discuss their or anyone else’s child. 2.2 Describe the importance of adult relationships as role models for children and young people It is important that the children see a good working relationship between adults because if they see tension between the adults the child or children will pick up on this. They may think that this is normal and start being like that themselves. Adults must set a good exampl e to the children and young people, being a good role model is important as you are there day in day out and they will learn from you. If you go in and they think that you are not interested it is going to impact negatively on them. 3.1 Describe how communication with children and young people differs across different ages and stages of development Communication differs between different ages and stages of development, people tend to use baby talk when talking to babies and toddlers which is ok but the need to know the correct words for things as it will make it difficult for them when they go to school. When they start school they will learn with phonics this will help them to learn to read and write, in schools now there are many children and young people who don’t have English as their first language so learning has to be adapted for their needs. Some children and young people’ levels understanding are not the same as others so they perhaps need a little more help and would require one to one help with certain subjects. 3.4 Describe how to adapt communication to meet different communication needs There are a many different communication needs within a school, for example hearing and speech diffi culties and ESOL (English speakers of other languages), They will all need extra help as people with hearing problems will require one to one as they may use sign language or lip reading the TA may need special training for this, you can also use picture cards or write things down. It may be easier for someone with speech problems to practice writing them down first before trying to say them and listening to someone else pronounce them first to help. With people who have English as their second language it will be more beneficial if they hear someone speaking the words to help with their pronunciation. When helping someone with anything whether they have difficulties or not it is important to speak slower pronounce things accurately and be patient. 3.5 Describe how to deal with disagreements between the practitioner and children and young people In setting the TA must diffuse any disagreements between children, there are often fallouts in  the playground over who had what first, as a TA I would say that the child who had it first could have it for 5 more minutes then it would be the other child’s turn. In my setting if a child does not do as they are told they will get a warning and if they continue misbehaving they will get a verbal warning, if the still do no adhere then they will get put on a stage. This will then be reported to the parents at the end of the day. If dealing with a disagreement between myself and other adults I would try to diffuse the situation by remaining calm seeking advice from a member of staff and I would also speak to the head of the school to find of what the complaints and grievance procedures are for that school. You would not necessarily need to use the procedures but it would be useful to know for future reference. When dealing with disagreements with adults you need to use the same methods as when dealing with children and young people, stay calm and don’t shout as shouting will only make matters worse. You also need to be discreet as people will not appreciate people gossiping about the situation. 4.1 Identify relevant legal requirements and procedures covering confidentiality, data protection and the disclosure of information * The children’s act 2004 * SEN Code of practice 2001 * Human Rights act 1998 * Freedom of Information act 2000 4.3 Identify the kinds of situations when confidentiality protocols must be breached * OFSTED Safeguarding in schools: best practice September 2011 No 100240 * Risk of serious harm * Where an adult is aware that a child is involved in criminal activities * Illness

Synthesis of chloropentaaminecobalt(lll) chloride Essays

Synthesis of chloropentaaminecobalt(lll) chloride Essays Synthesis of chloropentaaminecobalt(lll) chloride Paper Synthesis of chloropentaaminecobalt(lll) chloride Paper Insert the tube into the MSB and take a mental average of the fluctuating reading. 5. Repeat the previous step three times. 6. If the MSB displays a negative number, the coordination complex is diamagnetic and no further steps are necessary. 7. Determine how many unpaired electrons reside on the cobalt. E. Interpreting Infrared Spectrum 1. Assign the bands of the infrared spectrum of the complex. Results A. Synthesizing Carbonatotetraamminecobalt (III) nitrate: [Co(NH3)4CO3]NO3 The first attempt to dissolve the ammonium carbonate in 30. 0 mL of water failed because some chunks still remained. It was important to grind the ammonium carbonate down to a fine powder because the dissolution process took place very slowly and bigger chunks would not have dissolved. After all of the 10. 012 g of ammonium carbonate was dissolved, the liquid remained clear. The addition of 7. 56 g of cobalt nitrate to 15. 0 mL of water was very fluent and took on a color between dark purple and maroon. When the ammonium carbonate and cobalt nitrate solutions were added together, the new mixture was a blood red. After the mixture was stirred, however, it darkened and became nearly black. The 4. 0 mL of 30% H2O2 solution which was slowly added caused the mixture to bubble, sizzle and gain heat, while staying black. While the solution, which was poured into a large crucible, was concentrated over a Bunsen burner, evaporation occurred very slowly. During evaporation, the solution bubbled a little, gas was evolved, and the dissolution of 2. 49 g of ammonium carbonate in the hot solution was visible due to tiny bubbles. After the evaporation was complete and the volume had dropped to 48 mL, the solution had the same appearance. However, after suction filtering the solution, the color became a lighter purple. After the cold water bath, it looked somewhat powdery on the bottom. Filtering a second time resulted in only a pink/purple powder which appeared somewhat crystalline. When the solid was mixed with a scupula during the 10 minute drying process, it looked a lot more like crystals. The final mass of the crystals was 3. 039 g. The balanced equation for the synthesis of carbonatotetraamminecobalt (III) nitrate is shown below as well as the calculations for determining percent yield. 2Co(NO3)2 + 6NH3 + 2(NH4)2CO3 + H2O2 2[Co(NH3)4CO3]NO3 + 2NH4NO3 + 2H2O Theoretical Yield: Density of NH3 (liquid) = . 628 g/ml Density of 30% H2O2 = 1. 11 g/ml Moles of NH3 = (30 ml)(. 628 g/ml)/(17. 031 g/mol) = 1. 20 mol Moles of H2O2 = (4. 0 ml)(1. 11 g/ml)/(34. 015 g/mol) = . 131 mol Moles of [Co(H2O)6](NO3)2 = . 025 mol Moles of (NH4)2CO3 = . 105 mol Limiting Reactant = [Co(H2O)6](NO3)2 (. 025 mol of [Co(H2O)6](NO3)2)(2 mol of [Co(NH3)4CO3]NO3 / 2 mol [Co(H2O)6](NO3)2) = .025 mol of [Co(NH3)4CO3]NO3 (. 025 mol of [Co(NH3)4CO3]NO3)(249. 066g) = 6. 22 g Percent Yield (Actual Yield/Theoretical Yield)(100) = (3. 039 g/6. 22 g)(100) = 48. 86 % Yield B. Measuring Absorbance Spectroscopy. Two distinct peaks of intensity were noticeable for the absorbance spectrum of the cobalt solution between 350 to 650 nm. Below are the calculations for determining the mass of crystals required to create a solution of the right concentration to produce a spectrum of absorbance at approximately 0. 6. A = ? lC 0. 6 = (100 M-1cm-1)(1 cm)(C mol/L) 0. 006 M = C mol/L mol = . 0006 .0006 mol = (mass)/(249. 037 g/mol) mass = 0. 149 g [Co(NH3)4CO3]NO3 The mass of [Co(NH3)4CO3]NO3 added to 100 mL of water was 0. 149 g. Initially, the crystals were dissolved in a beaker to ease stirring. After dissolving, the solution turned purple. The solution was poured into an Erlenmeyer flask and filled with more water to the line on the flask. Below are the calculations for determining the extinction coefficient at each lambda max. The graph for the absorption spectrum is attached. .579 = (? max)(1 cm)(. 006 M) ?max = 96. 5 .519 = (? max)(1 cm)(. 006 M) ?max = 86. 5 C. Measuring conductivity Below are the calculations for preparing a . 001 M solution of the cobalt complex in 100 mL of water. (. 001 M/1000 mL) = (. 0001 mol/100 mL) .0001 mol = (mass/249. 037 g/mol) mass = .025 g. Below are the calculations for finding k, the correction factor. k = literary value/actual value Literary value = 1384 i seimens Actual value of KCl = 1420 i seimens k = (1384/1420) = . 975 Below are the calculations for finding the conductance of the cobalt solution. Probe reading of cobalt solution = 90 i seimens [((1000)(90 i seimens))(. 975)/. 002M](1x10e-6) = 43. 88 i seimens D. Measuring Magnetic Susceptibility Average empty tube reading = -004 Mass of empty tube = . 884 g Mass of tube with crystals = 1. 022 g Height of chemical in capillary rod = 3. 25 cm. Average filled tube reading = -004 (diamagnetic) Temperature of the room = 18. 6 ? C No calculations required. E. Interpreting Infrared Spectrum [Co(NH3)4CO3]NO3 IR spectrum: spikes at frequencies(cm-1) of 280, 500, 830, 1290, 1380, 1600, and 3300. [Co(NH3)5Cl]Cl2 IR spectrum: spikes at frequencies(cm-1) of 830, 1290, 1550, 3200. NaNO3 IR spectrum: spikes at frequencies(cm-1) of 830 and 1380. Discussion A problem occurred during the conductivity measurements of the cobalt complex. The expected values for conductance were between 118 and 131, but the actual calculated value was 43. 88 microseimens. Clearly, the problem arose during the probe reading in the cobalt solution. It is possible that the probes reading was skewed because it made contact with the glass wall of the beaker. This problem would have definitely lowered the reading relative to what it should have been. The absorbance spectrum of the cobalt complex on the wavelength interval 350-650 nm displayed two distinct peaks, meaning that both ions of the coordination compound were separated. This suggests strongly that the coordination compound was indeed synthesized correctly. The absorption intensities at both lambda maxes were relatively close, around 0. 6. These absorption values were used in the Beers Law equation to solve for the molar absorbance, also called the extinction coefficient. Both molar absorbance values are fairly close to 100, but deviations of 4 and 14 imply that some impurities still remain in the compound, possibly left over from the evaporation process. The coordination compound characterization via magnetic susceptibility was rather simple data requiring no calculations. The reason for this is that the magnetic susceptibility reading of the crystal-filled glass tube was equal to the reading of the empty tube, and that both were negative values. Negative values signify that the coordination compound is diamagnetic, which means that no unpaired electrons are present. The reason for the pairing of electrons can be explained with crystal field splitting. When electrons are introduced to d-orbitals, a change in energy occurs. Electrons will move to orbitals with the lowest possible energy. The ideal behavior for electrons after occupying the dxy, dx2, and dyz orbitals is to pair with the electrons already in these same orbitals. This is true only if ? E, or the energy difference from these orbitals to the dx2-y2 and dz2 orbitals, is greater than the energy cost for pairing with electrons in the lower orbitals. In the case of the cobalt complex, the spin pairing energy is much less than ? E, causing the electrons to pair in the lower energy orbitals. This pairing makes the complex a low-spin complex, implying that it is in fact diamagnetic. The goal of the infrared spectroscopy analysis was to prove that the cobalt coordination compound which was created during this experiment was actually created instead of a different compound with similar properties and bonds. [Co(NH3)5Cl]Cl2 and NaNO3 were available to compare with the infrared spectrum of [Co(NH3)5CO3]NO3. Clearly, [Co(NH3)5CO3]NO3 cannot be the same compound as NaNO3 because they only share one infrared band. Both coordination compounds have a band at 3300 cm-1 which corresponds to a N-H stretch, one at 1600 cm-1 corresponding to N-H bending, one at 1300 cm-1 corresponding to N-H symmetric bending, and one at 830 cm-1 corresponding to N-H bending. The most important difference between these coordination compounds lies in the common spike of [Co(NH3)5CO3]NO3 and NaNO3 at 1380 cm-1. Because these two compounds share this spike while the Cl coordination compound does not, the 1380 cm-1 peak must represent an N-O bond, which is the most significant spike on the NaNO3 spectrum as would be expected. During the synthesis of carbonatotetraamminecobalt (III) nitrate, several factors could have contributed to the relatively low quantity of crystals formed in terms of the percent yield. After calculations, it was concluded that 6. 22 grams of crystals should have been produced. However, only 3. 039 grams was actually produced. One of these factors that may have contributed to the low percent error of 48. 86% is the short evaporation stage. Since time was a factor during the experiment, the solution may not have been given enough time to evaporate any impurities. While the final volume of the solution was verified to be 48 mL, under the designated 50 mL, more impurities could have evaporated. If the solution had sat above a Bunsen burner for a greater length of time, it would have undoubtedly become more concentrated. Another factor which possibly contributed to a low percent yield is measurement errors. Although a good level of confidence can be felt about whether or not the right amounts were added, there is always room for error. A simple miscalculation or slight deviation in a measurement could have thrown off the remainder of the synthesis. Furthermore, a very obvious source of error can be found regarding the filtering system. The crystal product is quite soluble in water for the fact that its ions can be easily separated. For this reason, ice cold water was used whenever contact had to be made with the crystals; the low temperature of the water prevents the dissolution of the crystals to some extent. In the filter, some of the crystals could have dissolved and fallen through, which would have resulted in a poor percent yield. In general, this experiment ran very smoothly and achieved its purpose of providing detailed information regarding the properties and synthesis processes of a transition metal coordination compound. To improve the results of percent yield and perhaps to improve the results in many areas of characterization, the evaporation stage should be lengthened to facilitate the removal of remaining impurities.

Metrosexuality response Essays

Metrosexuality response Essays Metrosexuality response Paper Metrosexuality response Paper Summarize the article. What contribution does this article offer to the conversation of masculinity? Through the analysis of recent articles and documentaries, one may conclude that the true definition of man and masculinity may be hard to define, much less conceptualize. In such ways, masculinity is often defined by what it is not. With this in mind, through the analysis of the article, Managing Masculinity: The Metrosexual Moment, by Helene Shugart, one may see that these lines have once again been blurred. As mentioned, Masculine gender identity is never stable; its terms are ontinually being re-defined and re-negotiated, the gender performance continually being restaged. In congruence, Shugart presents us with the idea of metrosexuality. The definition of metrosexuality is: a usually urban heterosexual male given to enhancing his personal appearance by grooming, beauty treatments, and fashionable clothes. This very definition may lead one to question all previous knowledge and guidelines of masculinity. Such a definition has lead to problems in distinguishing between masculinity and femininity, thus resulting in the, masculinity risis. The article seeks to address these issues as well as the changing concepts of identity, status, and privilege. As we have learned through this article and previous analyses, commercialization has a highly pervasive influence on masculinity. As mentioned in the article, some scholars trace commercial masculinity back to the 1950s, yet it is still pervasive in contemporary popular culture. Most agree that the 1980s witnessed the start of a dramatic shift toward the objectification of the male body. As the article states this bservation is consistent with the notion that commercial masculinity may be best understood as a logical consequence of feminist challenges to cultural discourses and definitions of gender. In past discussions we have seen the continuous objectification of the female body, now it seems as though the tables have slightly shifted and in doing so raised the standard in commercial masculinity. With this in mind one may have seen the sudden birth of the, metrosexuality movement. Shugart addresses these commercialized issues in regards to the emergence of said ovement. The television show Queer Eye for the Straight Guy, the book that was spun off of the television series, and the popularly designated handbook of metrosexuality (The Metrosexual Guide to Style: A Handbook for the Modern Man) all further aided the growth and influence of this movement. Although the phenomenon was but brief it was significant to the extent that it thoroughly consumed the public consciousness for the better part of two years. The article mentions that, despite the ostensible promise of a union forged between heterosexual and gay men for edefining masculinity, Queer Eye ultimately reifies normative notions by defining homosexuality against masculinity. In congruence, metrosexuality challenges the normative masculinity. As gender barriers have grown more fluid, so has the male appeal of accessories, mentions in the above quote, with the questioning of normative masculinity came a marked reversal of the gendered tradition of self-improvement, which Faludi describes as the ornamentalisation of men. It should be known that gay men where essential to metrosexuality in US popular culture. As Shugart states, metrosexuality as rendered meaningful in this regard as a product of the intersection between normative, straight masculinity and gay, effeminate mascul inity. In the popular US discourse of metrosexuality, gay men were assigned very clearly defined roles, as drawn sharply against authentic -heterosexual†masculinity. Within the discourse of commercial masculinity, metrosexuality effectively consigned gay men the role of border agents located at the margins of gender and sexuality, charges with marshalling those borders and resolutely maintaining their continence even as they ollaborated closely with straight men. Straight men could collude with and capitalize on gay mens aberrant status in order to increase their cultural capital, both with women and in terms of economic and professional success, to which the gay men essentially functioned as link. Henceforth, the presence of gay men was vital within the metrosexual movement. Through analysis of the article, in congruence with past discussions, I feel that metrosexuality defies all previous accounts of masculinity. This defiance further blurs the lines between masculinity and femininity. Through my personal analysis, I conclude that a metrosexual male is no less masculine than a commercialized rough and tough fgure such as, Rocky Balboa. Although I am no closer to being able to clearly define the lines that encompass masculinity, I feel that this broader knowledge allows for a more open minded assessment. No two people are created equally, therefore one man cannot be held to the standards of another. Although this seems to be an unrealistic conclusion given todays society, one can only make strides towards this true definition of a man.